Driving a Greener Future: HKUST Engineering Develops Advanced Sustainable Energy Storage Technology for High-Performance and Safer Solid-State Lithium Batteries

A research team led by Prof. Yoonseob KIM, Associate Professor of the Department of Chemical and Biological Engineering at The Hong Kong University of Science and Technology (HKUST) has reported a significant breakthrough in lithium metal battery (LMB) technology. The team has successfully synthesized a novel single-crystalline 3D borate covalent organic framework (B-COF), which demonstrates exceptional performance as a solid-state electrolyte, thereby enhancing the performance of solid-state lithium batteries. This advancement promises safer and higher energy density solutions for electric vehicles and large-scale energy storage. The research paper, titled "Single-Crystalline Borate Covalent Organic Frameworks for Solid-State Lithium Metal Batteries", has been published in the prestigious journal Advanced Science.

Traditional LMBs face safety risks from lithium dendrite formation and rapid degradation due to unstable electrolyte interfaces. While Covalent Organic Frameworks (COFs) are promising electrolyte materials due to their porous structure and stability, most existing COFs are polycrystalline, which leads to significant interparticle resistance and limits their performance.

To address this issue, the research team utilized COF-303 as a template to construct a single-crystalline 3D B-COF with highly ordered ion channels. This single-crystalline nature significantly reduces intergrain resistance and facilitates uniform lithium deposition, effectively suppressing dendrite growth.

This work has achieved high performance in solid-state lithium batteries in the following areas:

• Exceptional Ion Conductivity and Selectivity: Achieved a remarkable ionic conductivity of 8.1 mS cm–1 at room temperature, with a Li+ transference number of 0.98 in a quasi-solid-state, ensuring rapid and selective ion movement.
• Superior Interface Stability and Safety: Supported stable lithium deposition and stripping for over 2,000 hours in symmetric cells, effectively suppressing hazardous dendrite formation.
• High Efficiency and Long-Term Durability: Full cells utilizing LiFePO4 cathodes demonstrated robust cycling with 91.8% capacity retention and 99.98% Coulombic efficiency over 600 cycles at 0.5C, delivering an initial capacity of 147 mAh g–1.

"Our research highlights the promising viability of single-crystalline 3D B-COFs as quasi-solid-state electrolytes. By eliminating the structural disorders found in polycrystalline materials, we have taken a significant step toward realizing high-performance, safe energy storage solutions that are crucial for a greener future," said Prof. Yoonseob KIM, co-corresponding author of the study.

This research was conducted collaboratively by teams led by Prof. Yoonseob KIM at HKUST and Prof. Yanming WANG from the Global Institute of Future Technology at Shanghai Jiao Tong University (SJTU). The co-first authors of the study include Dr. Ye TIAN, a PhD graduate; Dr. Xiaolong CHENG, a postdoctoral fellow from the Department of Chemical and Biological Engineering at HKUST, and Mr. Lei CHENG, a PhD candidate at SJTU.

(This news was originally published by the HKUST School of Engineering here.)